Nitration is a post-translational modification of mostly tyrosine residues that is caused by oxidation. First, a tyrosine radical is formed by one-electron oxidation followed by a reaction with nitrogen dioxide resulting in 3-nitrotyrosine. Lit.
λ / nm |
ε / M-1 cm-1 |
---|---|
214 | 0 |
240 | 0 |
245 | 0 |
250 | 2267 |
255 | 2646 |
260 | 3308 |
265 | 3783 |
270 | 4279 |
272 | 4321 |
274 | 4388 |
276 | 4521 |
278 | 4588 |
280 | 4563 |
282 | 4521 |
284 | 4642 |
286 | 4750 |
288 | 4608 |
290 | 4421 |
292 | 4225 |
294 | 3867 |
296 | 3496 |
298 | 3088 |
300 | 2833 |
302 | 2583 |
304 | 2383 |
306 | 2175 |
308 | 1921 |
310 | 1813 |
312 | 1725 |
314 | 1658 |
316 | 1650 |
318 | 1658 |
320 | 1679 |